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| Swanner, Elizabeth D.; Planavsky, Noah J.; Lalonde, Stefan; Robbins, Leslie J.; Bekker, Andrey; Rouxel, Olivier; Saito, Mak A.; Kappler, Andreas; Mojzsis, Stephen J.; Konhauser, Kurt O.. |
| Cobalt (Co) is a bio-essential trace element and limiting nutrient in some regions of the modern oceans. It has been proposed that Co was more abundant in poorly ventilated Precambrian oceans based on the greater utilization of Co by anaerobic microbes relative to plants and animals. However, there are few empirical or theoretical constraints on the history of seawater Co concentrations. Herein, we present a survey of authigenic Co in marine sediments (iron formations, authigenic pyrite and bulk euxinic shales) with the goal of tracking changes in the marine Co reservoir throughout Earthʼs history. We further provide an overview of the modern marine Co cycle, which we use as a platform to evaluate how changes in the redox state of Earthʼs surface were... |
| Tipo: Text |
Palavras-chave: Cobalt; Trace element proxies; Ocean redox; Shale; Iron formation; Pyrite. |
| Ano: 2014 |
URL: http://archimer.ifremer.fr/doc/00174/28575/26986.pdf |
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| Lemonnier, Hugues; Royer, Florence; Caradec, Florian; Lopez, Etienne; Hubert, Clarisse; Rabiller, Emilie; Desclaux, Terence; Fernandez, Jean-michel; Andrieux-loyer, Francoise. |
| The gill is the organ by which many toxic metals are taken up by crustaceans. Iron is known to precipitate at its surface, a phenomenon recently observed in some tropical aquaculture ponds. The present study uses a field approach to understand better the environmental conditions and ecological processes involved in this deposit. Because shrimp are exposed to reduced products originating from organic waste accumulated in the sediment, spatial variation in pH, redox potential and concentrations of dissolved metals in pore water were investigated in these ponds. Total organic carbon, acid volatile sulfide and pyrite were also analyzed in the solid phase. Fe2+ in pore waters showed high spatial variability between ponds and within the same pond with... |
| Tipo: Text |
Palavras-chave: Shrimp aquaculture sustainability; Iron deposits; Gills; Sediment acidification; Redox dynamic; Dynamic of metals; Pyrite. |
| Ano: 2021 |
URL: https://archimer.ifremer.fr/doc/00678/79026/81450.pdf |
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| Mexias,André S.; Berger,Gilles; Gomes,Márcia E.B.; Formoso,Milton L.L.; Dani,Norberto; Frantz,José C.; Bongiolo,Everton M.. |
| A geochemical modeling of gold deposition was performed using the EQ3/EQ6 software package using conditions inferred from geological, petrographic, geochemical and fluid inclusion data from the Bloco do Butiá gold mine, Lavras do Sul, RS. Gold in the mine occurs only in the pyrite structure (invisible gold). The pyrite occurs associated with white mica (phengite) in the zone of phyllic alteration. The process of gold deposition showed to be related to temperature and pH decrease. The pH decrease was fundamental to gold deposition by destabilization of sulfur species [Au(HS)2- , HAu(HS)2(0) and Au(HS)0] dissolved in the aqueous solution, being Au(HS)0 the main gold transporting complex. The addition of KCl is hard to accept as cause of gold precipitation... |
| Tipo: Info:eu-repo/semantics/article |
Palavras-chave: Geochemical modeling; Gold; Pyrite; Sulfur; Fluid-rock interaction. |
| Ano: 2005 |
URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652005000400010 |
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